竹鸡鸣声特征分析

本文用计算机鸣声分析技术，从时域、频域和短时能量等方面对杭州地区竹鸡早春的鸣声特征进行了分析.竹鸡鸣叫一般有5-11声，每声均为3个音节，各声的时域波形和功率谱特性均不相同.开始鸣声短促，往后持续时间逐渐延长，末声是第1声的1. 82倍，主要是各音节之间的间隔时间和第，音节的持续时间逐次延长，而第I和第1音节的持续时间逐渐缩短.同时，相同音节的BS的MPF渐次降低，第I、I音节分别降低了33%和40%.随着声序的增加，各音节的Bw渐次变窄.从各音节的前48ms声段分析可知，三个音节的RA变化各不相同，SS。的RA渐趋升高，SS:的RA在第4,5声最高，}3的RA在第7,8声最高.每声的短时能量分布也不同，前几声各音节都有较高的能量，后来第，音节能量逐渐降低，第，音节能量渐渐后移.整个鸣叫过程中，纯音平均约占7100,频率变化范围约在1500-3120H:之间     

Extremal functions for the Moser-Trudinger inequalities on compact Riemannian manifolds

Let (M,g) be a compact Riemannian manifold without boundary, and (N,g) a compact Riemannian manifold with boundary. We will prove in this paper that the and can be attained. Our proof uses the blow-up analysis.     

Direct Z‐Scheme Hetero‐phase Junction of Black/Red Phosphorus for Photocatalytic Water Splitting

Black phosphorus (BP) has recently drawn attention in photocatalysis for its optical properties. However, limited by the rapid recombination of photogenerated carriers, the use of BP for photocatalytic water splitting still remains a huge challenge. Herein, we prepare a black/red phosphorus (BP/RP) hetero‐phase junction photocatalyst by a wet‐chemistry method to promote the interfacial charge separation and thus achieve Z‐scheme photocatalytic water splitting without using sacrificial agents. The Z‐scheme mechanism was confirmed by time‐resolved transient absorption spectroscopy. This work provides a novel insight into the interface design of hetero‐phase junction with atomic precision.     

Dynamic relaying properties of a β-turn peptide in long-range electron transfer

The relay stations play a significant role in long-range charge hopping transfer in proteins. Although studies have clarified that many more protein structural motifs can function as relays in charge hopping transfers by acting as intermediate charge carriers, the relaying properties are still poorly understood. In this work, taking a β-turn oligopeptide as an example, we report a dynamic character of a relay with tunable relaying properties using the density functional theory calculations. Our main finding is that a β-turn peptide can serve as an effective electron relay in facilitating long-range electron migration and its relay properties is vibration-tunable. The vibration-induced structural transient distortions remarkably affect the lowest occupied molecular orbital (LUMO) energy, vertical electron affinity and electron-binding mode of the β-turn oligopeptide and the singly occupied molecular orbital (SOMO) energy of the corresponding electron adduct and thus the relaying properties. Different vibration modes lead to different structural distortions and thus have different effects on the relaying properties and ability of the β-turn peptide. For the relaying properties, there approximately is a linear negative correlation of electron affinity with the LUMO energy of the β-turn or the SOMO energy of its electron adduct. Besides, such relaying properties also vary in the vibration evolution process, and the electron-binding modes may be tunable. As an important addition to the known static charge relaying properties occurring in various protein structural motifs, this work reports the dynamic electron-relaying characteristics of a β-turn oligopeptide with variable relaying properties governed by molecular vibrations which can be applied to different proteins in mediating long-range charge transfers. Clearly, this work reveals molecular vibration effects on the electron relaying properties of protein structural motifs and provides new insights into the dynamics of long-range charge transfers in proteins. © 2018 Wiley Periodicals, Inc.     

Late-Stage Peptide Macrocyclization by Palladium-Catalyzed Site-Selective C−H Olefination of Tryptophan

Transition-metal-catalyzed C−H activation has shown potential in the functionalization of peptides with expanded structural diversity. Herein, the development of late-stage peptide macrocyclization methods by palladium-catalyzed site-selective C(sp²)−H olefination of tryptophan residues at the C2 and C4 positions is reported. This strategy utilizes the peptide backbone as endogenous directing groups and provides access to peptide macrocycles with unique Trp–alkene crosslinks.     

Luminescent Thin Films Enabled by CsPbX3 (X=Cl,Br, I) Precursor Solution

Inorganic cesium lead halide perovskite nanocrystals are candidates for lighting and display materials due to their outstanding optoelectronic properties. However, the dissolution issue of perovskite nanocrystals in polar solvents remains a challenge for practical applications. Herein, we present a newly designed one-step spin-coating strategy to prepare a novel multicolor-tunable CsPbX₃ (X=Cl, Br, I) nanocrystal film, where the CsPbX₃ precursor solution was formed by dissolving PbO, Cs₂CO₃, and CH₃NH₃X into the ionic liquid n-butylammonium butyrate. The as-designed CsPbX₃ nanocrystal films show high color purity with a narrow emission width. Also, the blue CsPb(Cl/Br)₃ film demonstrates an absolute photoluminescence quantum yields (PLQY) of 15.6 %, which is higher than 11.7 % of green CsPbBr₃ and 8.3 % of red CsPb(Br/I)₃ film. This study develops an effective approach to preparing CsPbX₃ nanocrystal thin films, opening a new avenue to design perovskite nanocrystals-based devices for lighting and display applications.